Manufacturing Technology 2019, 19(5):740-744 | DOI: 10.21062/ujep/364.2019/a/1213-2489/MT/19/5/740

Magnesium Composite Materials Prepared by Extrusion of Chemically Treated Powders

Drahomír Dvorský, Jiří Kubásek, Dalibor Vojtěch
University of Chemistry and Technology Prague, Faculty of Chemical Technology, Department of Metals and Corrosion Engineering, Technická 5 166 28 Praha 6 - Dejvice, Czech Republic

This paper is focused on the preparation of the magnesium composite materials by extrusion of the chemically treated powders. Microstructures with partially preserved borders between particles containing specific elements depending on the preparation method were created by extrusion. Compressive mechanical properties of extruded chemically treated powders were similar to material prepared from atomized powder. The corrosion rate was reduced by three times in the case of chemically treated powder compared to the pure Mg. Ignition temperature of the chemically treated powder increased by up to 200 °C compared to the atomized powder, while ignition temperatures of the extruded samples were only slightly improved.

Keywords: Composite material, corrosion, powder metallurgy, extrusion, ignition temperature
Grants and funding:

Czech Science Foundation (project no. GA19-08937S).
Specific university research MSMT No 21-SVV/2019 for the financial support of this research.

Published: October 1, 2019  Show citation

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Dvorský D, Kubásek J, Vojtěch D. Magnesium Composite Materials Prepared by Extrusion of Chemically Treated Powders. Manufacturing Technology. 2019;19(5):740-744. doi: 10.21062/ujep/364.2019/a/1213-2489/MT/19/5/740.
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References

  1. LIU, C., LU, S., FU, Y., ZHANG, H. (2015). Flammability and the oxidation kinetics of the magnesium alloys AZ31, WE43, and ZE10. In: Corrosion Science, Vol. 100, No., pp. 177-185. Go to original source...
  2. SHIH, T.-S., LIU, J.-B., WEI, P.-S. (2007). Oxide films on magnesium and magnesium alloys. In: Materials Chemistry and Physics, Vol. 104, No. 2, pp. 497-504. Go to original source...
  3. AYDIN, D. S., BAYINDIR, Z., HOSEINI, M., PEKGULERYUZ, M. O. (2013). The high temperature oxidation and ignition behavior of Mg-Nd alloys part I: The oxidation of dilute alloys. In: Journal of Alloys and Compounds, Vol. 569, No., pp. 35-44. Go to original source...
  4. ZHOU, N., ZHANG, Z., DONG, J., JIN, L., DING, W. (2013). Selective oxidation behavior of an ignition-proof Mg-Y-Ca-Ce alloy. In: Journal of Rare Earths, Vol. 31, No. 10, pp. 1003-1008. Go to original source...
  5. PAN, F., YANG, M., CHEN, X. (2016). A Review on Casting Magnesium Alloys: Modification of Commercial Alloys and Development of New Alloys. In: Journal of Materials Science & Technology, Vol. 32, No. 12, pp. 1211-1221. Go to original source...
  6. NING, Z. L., ZHAO, X. Y., LUO, A. A., LIU, H. H., LIANG, W. Z., HUANG, Y. J., CAO, F. Y., SUN, J. F. (2017). The melt protection mechanism of an SO2/CO2 gas mixture for a magnesium-rare-earth based alloy. In: Journal of Alloys and Compounds, Vol. 722, No., pp. 101-107. Go to original source...
  7. FAN, J., CHEN, Z., YANG, W., FANG, S., XU, B. (2012). Effect of yttrium, calcium and zirconium on ignition-proof principle and mechanical properties of magnesium alloys. In: Journal of Rare Earths, Vol. 30, No. 1, pp. 74-78. Go to original source...
  8. CHEN, H., CHANG, L., JIE, Y. (2017). Reaction kinetics of MgF2 powder in air at high temperature. In: Corrosion Science, Vol. 126, No., pp. 121-126. Go to original source...
  9. MONDET, M., BARRAUD, E., LEMONNIER, S., GUYON, J., ALLAIN, N., GROSDIDIER, T. (2016). Microstructure and mechanical properties of AZ91 magnesium alloy developed by Spark Plasma Sintering. In: Acta Materialia, Vol. 119, No., pp. 55-67. Go to original source...
  10. TEKUMALLA, S., GUPTA, M. (2017). An insight into ignition factors and mechanisms of magnesium based materials: A review. In: Materials & Design, Vol. 113, No., pp. 84-98. Go to original source...
  11. CZERWINSKI, F. (2014). Controlling the ignition and flammability of magnesium for aerospace applications. In: Corrosion Science, Vol. 86, No., pp. 1-16. Go to original source...
  12. GU, X.-N., ZHENG, Y.-F. (2010). A review on magnesium alloys as biodegradable materials. In: Frontiers of Materials Science in China, Vol. 4, No. 2, pp. 111-115. Go to original source...
  13. STAIGER, M. P., PIETAK, A. M., HUADMAI, J., DIAS, G. (2006). Magnesium and its alloys as orthopedic biomaterials: A review. In: Biomaterials, Vol. 27, No. 9, pp. 1728-1734. Go to original source...
  14. AHMADKHANIHA, D., JÄRVENPÄÄ, A., JASKARI, M., SOHI, M. H., ZAREI-HANZAKI, A., FEDEL, M., DEFLORIAN, F., KARJALAINEN, L. P. (2016). Microstructural modification of pure Mg for improving mechanical and biocorrosion properties. In: Journal of the Mechanical Behavior of Biomedical Materials, Vol. 61, No., pp. 360-370. Go to original source...
  15. KUBÁSEK, J., DVORSKÝ, D., ČAVOJSKÝ, M., VOJTĚCH, D., BERONSKÁ, N., FOUSOVÁ, M. (2017). Superior Properties of Mg-4Y-3RE-Zr Alloy Prepared by Powder Metallurgy. In: Journal of Materials Science & Technology, Vol. 33, No. 7, pp. 652-660. Go to original source...
  16. WU, G., IBRAHIM, J. M., CHU, P. K. (2013). Surface design of biodegradable magnesium alloys - A review. In: Surface and Coatings Technology, Vol. 233, No., pp. 2-12. Go to original source...
  17. DVORSKÝ, D., KUBÁSEK, J., VOJTĚCH, D. (2015). Hydroxyapatite in Materials for Medical Applications In: Manufacturing Technology, Vol. 15, No. 6, pp. 969-973. Go to original source...
  18. DVORSKY, D., KUBASEK, J., VOJTECH, D. (2017). Corrosion protection of WE43 magnesium alloy by fluoride conversion coating. In: Manufacturing Technology, Vol. 17, No. 4, pp. 440-446. Go to original source...
  19. REN, M., CAI, S., LIU, T., HUANG, K., WANG, X., ZHAO, H., NIU, S., ZHANG, R., WU, X. (2014). Calcium phosphate glass/MgF2 double layered composite coating for improving the corrosion resistance of magnesium alloy. In: Journal of Alloys and Compounds, Vol. 591, No., pp. 34-40. Go to original source...
  20. JO, J.-H., KANG, B.-G., SHIN, K.-S., KIM, H.-E., HAHN, B.-D., PARK, D.-S., KOH, Y.-H. (2011). Hydroxyapatite coating on magnesium with MgF2 interlayer for enhanced corrosion resistance and biocompatibility. In: Journal of Materials Science: Materials in Medicine, Vol. 22, No. 11, pp. 2437-2447. Go to original source...
  21. SUN, J. E., WANG, J., JIANG, H., CHEN, M., BI, Y., LIU, D. (2013). In vivo comparative property study of the bioactivity of coated Mg-3Zn-0.8Zr alloy. In: Materials Science and Engineering: C, Vol. 33, No. 6, pp. 3263-3272. Go to original source...
  22. YAN, T., TAN, L., ZHANG, B., YANG, K. (2014). Fluoride Conversion Coating on Biodegradable AZ31B Magnesium Alloy. In: Journal of Materials Science & Technology, Vol. 30, No. 7, pp. 666-674. Go to original source...
  23. LIU, X., ZHEN, Z., LIU, J., XI, T., ZHENG, Y., GUAN, S., ZHENG, Y., CHENG, Y. (2015). Multifunctional MgF2/Polydopamine Coating on Mg Alloy for Vascular Stent Application. In: Journal of Materials Science & Technology, Vol. 31, No. 7, pp. 733-743. Go to original source...
  24. DVORSKY, D., KUBASEK, J., VOJTECH, D. (2018). A new approach in the preparation of biodegradable Mg-MgF2 composites with tailored corrosion and mechanical properties by powder metallurgy. In: Materials Letters, Vol. 227, No., pp. 78-81. Go to original source...
  25. DVORSKÝ, D., KUBÁSEK, J., VOJTĚCH, D., VOŇAVKOVÁ, I., VESELÝ, M., ČAVOJSKÝ, M. (2017). Structure and mechanical characterization of Mg-Nd-Zn alloys prepared by different processes. In: IOP Conference Series: Materials Science and Engineering, Vol. 179, No. 1, pp. 012018.
  26. RALSTON, K. D., BIRBILIS, N., DAVIES, C. H. J. (2010). Revealing the relationship between grain size and corrosion rate of metals. In: Scripta Materialia, Vol. 63, No. 12, pp. 1201-1204. Go to original source...
  27. DVORSKY, D., KUBASEK, J., VOJTECH, D., CAVOJSKY, M. (2016). Structure and mechanical properties of WE43 prepared by powder metallurgy route. In: Manufacturing Technology, Vol. 16, No. 5, pp. 896-902. Go to original source...
  28. DVORSKÝ, D., KUBÁSEK, J., KRISTIANOVÁ, E., VOJTĚCH, D. (2018). Corrosion resistant magnesium-based composite material with MgF2 continuous network prepared by powder metallurgy. In: Manufacturing Technology, Vol. 18, No. 5, pp. 737-741. Go to original source...

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