Manufacturing Technology 2022, 22(4):423-428 | DOI: 10.21062/mft.2022.049

CoCrFeNiTi High Entropy Alloy Prepared via Mechanical Alloying and Spark Plasma Sintering

Petr Kratochvíl ORCID..., Filip Průša ORCID...
University of Chemistry and Technology Prague, Department of Metals and Corrosion Engineering Technická 5, 166 28 Prague 6, Czech Republic

Mechanical alloying and subsequent compaction with spark plasma sintering was chosen for the fabrication of investigated CoCrFeNiTi alloy method. The alloy was characterized in terms of chemical and phase composition with X-ray fluorescence spectroscopy and X-ray diffraction spectrometry, respectively. The microstructure was examined using light microscopy and scanning electron microscopy equipped with an energy dispersion spectrometer. The alloy showed an ultra-fine grained uniform microstructure composed mainly of an FCC solid solution with a volume fraction of HCP Laves phases. Regarding mechanical properties, the prepared specimen reached an ultimate compressive strength of 1340 MPa with the hardness of 757 HV 30. The wear rate of the sample reached 1.19 · 10-4 mm3·N-1·m-1 showing traces of adhesive-abrasion wear mechanism.

Keywords: High entropy alloys, Mechanical alloying, Spark plasma sintering, Mechanical properties
Grants and funding:

This research was financially supported by Czech Science Foundation (grant No. 21-11313S)

Received: April 20, 2022; Revised: June 29, 2022; Accepted: September 9, 2022; Prepublished online: October 6, 2022; Published: October 17, 2022  Show citation

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Kratochvíl P, Průša F. CoCrFeNiTi High Entropy Alloy Prepared via Mechanical Alloying and Spark Plasma Sintering. Manufacturing Technology. 2022;22(4):423-428. doi: 10.21062/mft.2022.049.
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References

  1. B. CANTOR, I. T. H. CHANG, P. KNIGHT and A. J. B. VINCENT, Microstructural development in equiatomic multicomponent alloys, Materials Science and Engineering: A, 375-377 (2004), pp. 213-218. Go to original source...
  2. T. FUJIEDA, M. CHEN, H. SHIRATORI, K. KUWABARA, K. YAMANAKA, Y. KOIZUMI, A. CHIBA and S. WATANABE, Mechanical and corrosion properties of CoCrFeNiTi-based high-entropy alloy additive manufactured using selective laser melting, Additive Manufacturing, 25 (2019), pp. 412-420. Go to original source...
  3. M. A. HAQ, N. S. A. EOM, N. SU, H. LEE, T. S. KIM and B. S. KIM, Powder interface modification for synthesis of core-shell structured CoCrFeNiTi high entropy alloy composite, Applied Surface Science, 506 (2020), pp. 144925. Go to original source...
  4. J. JOSEPH, P. HODGSON, T. JARVIS, X. WU, N. STANFORD and D. M. FABIJANIC, Effect of hot isostatic pressing on the microstructure and mechanical properties of additive manufactured AlxCoCrFeNi high entropy alloys, Materials Science and Engineering: A, 733 (2018), pp. 59-70. Go to original source...
  5. V. KUCERA, F. PRUSA and D. VOJTECH, Processing of Al-Fe Scraps by Powder Metallurgy, Manufacturing Technology Journal, 16 (2016), pp. 726-732. Go to original source...
  6. S. LIU, C. M. GROHOL and Y. C. SHIN, High throughput synthesis of CoCrFeNiTi high entropy alloys via directed energy deposition, Journal of Alloys and Compounds, 916 (2022), pp. 165469. Go to original source...
  7. F. PRUSA, A. SENKOVA, D. VOJTECH, J. CAPEK and A. BERNATIKOVA, High Entropy Alloys Prepared by Combination of Mechanical Alloying and Spark Plasma Sintering, Manufacturing Technology Journal, 16 (2016), pp. 1350-1354. Go to original source...
  8. F. PRUSA, D. VOJTECH, A. BERNATIKOVA and D. DVORSKY, Mechanical Alloying: A Way How to Improve Properties of Aluminium Alloys, Manufacturing Technology Journal, 15 (2015), pp. 1036-1043. Go to original source...
  9. F. PRŮŠA, A. ŠENKOVÁ, V. KUČERA, J. ČAPEK and D. VOJTĚCH, Properties of a high-strength ultrafine-grained CoCrFeNiMn high-entropy alloy prepared by short-term mechanical alloying and spark plasma sintering, Materials Science and Engineering: A, 734 (2018), pp. 341-352. Go to original source...
  10. G. D. SATHIARAJ and P. P. BHATTACHARJEE, Effect of starting grain size on the evolution of microstructure and texture during thermo-mechanical processing of CoCrFeMnNi high entropy alloy, Journal of Alloys and Compounds, 647 (2015), pp. 82-96. Go to original source...
  11. H. SHAHMIR, J. HE, Z. LU, M. KAWASAKI and T. G. LANGDON, Effect of annealing on mechanical properties of a nanocrystalline CoCrFeNiMn high-entropy alloy processed by high-pressure torsion, Materials Science and Engineering: A, 676 (2016), pp. 294-303. Go to original source...
  12. T.-T. SHUN, L.-Y. CHANG and M.-H. SHIU, Microstructures and mechanical properties of multiprincipal component CoCrFeNiTix alloys, Materials Science and Engineering: A, 556 (2012), pp. 170-174. Go to original source...
  13. P. WANG, P. HUANG, F. L. NG, W. J. SIN, S. LU, M. L. S. NAI, Z. DONG and J. WEI, Additively manufactured CoCrFeNiMn high-entropy alloy via pre-alloyed powder, Materials & Design, 168 (2019), pp. 107576. Go to original source...
  14. J.-W. YEH, Recent progress in high-entropy alloys, European Journal of Control - EUR J CONTROL, 31 (2006), pp. 633-648. Go to original source...
  15. J.-W. YEH, S.-K. CHEN, S.-J. LIN, J.-Y. GAN, T.-S. CHIN, T.-T. SHUN, C.-H. TSAU and S.-Y. CHANG, Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes, Advanced Engineering Materials, 6 (2004), pp. 299-303. Go to original source...
  16. K. ZHANG and Z. FU, Effects of annealing treatment on phase composition and microstructure of CoCrFeNiTiAlx high-entropy alloys, Intermetallics, 22 (2012), pp. 24-32. Go to original source...
  17. Y. ZHAO, Z. CHEN, K. YAN, W. LE and S. NASEEM, Effects of aging treatment on the evolution of precipitated phase in CoCrFeNiTi0.6 high entropy alloys, Journal of Alloys and Compounds, 887 (2021), pp. 161407. Go to original source...

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