Manufacturing Technology 2022, 22(5):598-604 | DOI: 10.21062/mft.2022.073
The Influence of Fe Content on Corrosion Resistance of secondary AlSi7Mg0.3 Cast Alloy with Increased Fe-content
- Faculty of Mechanical Engineering, Department of Materials Engineering, University of ®ilina, Univerzitná 8215/1, 010 26 ®ilina. Slovakia
Production of primary aluminium is energetically enormously expensive. The use of secondary (recycled) aluminium, has therefore a high potential to save money and energy while reducing the negative environmental impact of aluminium production. Although the properties of secondary aluminium alloys are generally comparable to those of primary aluminium alloys, the increased Fe content can lead to a significant reduction in the corrosion resistance of these alloys. Secondary (recycled) AlSi7Mg0.3 cast alloy with different iron contents (0.123, 0.454, 0.679 and 1.209 wt. %) in the as-cast and after heat treatment (T6) condition was investigated. The quantitative analysis was focused on the evaluation of the Fe-phases, especially the needle-like Al5FeSi phase. The corrosion resistance was measured by a rapid corrosion test (AUDI test). The corrosion damage of the surface was observed macroscopically. The results show that Fe content higher than 0.454 % has no significant effect on the amount and size of needle-like phases of Al5FeSi. The corrosion resistance is mainly influenced by the size and length of the Al5FeSi phases. Increased Fe content decreases the corrosion resistance of AlSi7Mg0.3 alloy and accelerates the initiation of corrosion.
Keywords: AlSi7Mg0.3 cast alloy, Fe-phase, Corrosion resistance, AUDI test
Grants and funding:
The research was supported by Scientific Grand Agency of Ministry of Education of Slovak Republic and Slovak Academy of Sciences, VEGA 01/0398/19, KEGA 016®U-4/2020, project to support young researchers at UNIZA, ID project 12715 (Kuchariková) and project 313011ASY4 “Strategic implementation of additive technologies to strengthen the intervention capacities of emergencies caused by the COVID-19 pandemic
Received: August 30, 2022; Revised: October 11, 2022; Accepted: December 6, 2022; Prepublished online: December 7, 2022; Published: December 11, 2022 Show citation
ACS | AIP | APA | ASA | Harvard | Chicago | IEEE | ISO690 | MLA | NLM | Turabian | Vancouver |
References
- Primary and secondary aluminum. Clinton Aluminum, 2021. https://www.clintonaluminum.com/primary-and-secondary-aluminum/.
- TULER, F. R., SCOTT-TAGGART, R. (2001). Aluminum. Encyclopedia of Materials: Science and Technology, pp. 97 - 100.
Go to original source...
- EAA_recycling brochure: RECYCLING ALUMINIUM A PATHWAY TO A SUSTAINABLE ECONOMY (2015), https://european-aluminium.eu/resource-hub/recycling-aluminium-a-pathway-to-a-sustainable-economy/
- KUCHARIKOVÁ, L., TILLOVÁ, E., BOKŮVKA, O. (2016). Recycling and properties of recycled aluminium alloys used in the transportation industry. In: Transport Problems, vol. 11, No. 2, pp. 117 - 122.
Go to original source...
- HANZA, S., et al. (2021). Corrosion investigation of Al-Si casting alloys in 0.6 M NaCl solution. In: Engineering Review, Vol. 41, No. 3, pp. 115 - 123.
Go to original source...
- SUKIMAN, N. L., et al. (2012). Durability and Corrosion of Aluminium and Its Alloys: Overview, Property Space, Techniques and Developments. In: Ahmad Z, (ed.), Aluminium Alloys - New Trends in Fabrication and Applications. IntechOpen. London. pp. 47 - 97. ISBN 978-953-51-0861-0.
- HADZIMA, B., LIPTÁKOVÁ, T. (2008). Základy elektrochemickej korózie kovov. ®ilinská univerzita v ®iline: EDIS, ISBN 978-80-8070-876-4.
- DOBKOWSKA, A., et al. (2020). The Comparison of the Microstructure and Corrosion Resistance of Sand Cast Aluminum Alloys. In: Archives of Metallurgy and Materials. Vol. 61, No. 1, pp. 209 - 212. ISSN 1733-3490.
Go to original source...
- SVOBODOVA, J., LUNAK, M., LATTNER, M. (2019). Analysis of the Increased Iron Content on the Corrosion Resistance of the AlSi7Mg0.3 Alloy Casting. In: Manufacturing Technology, Vol. 19, No. 6, pp. 1041 - 1046.
Go to original source...
- SHOUXUN, J., WENCHAO, Y., et. al. (2013). Effect of iron on the microstructure and mechanical property of Al-Mg-Si-Mn and Al-Mg-Si diecast alloys. In: Materials Science and Engineering: A, Vol. 564, pp. 130 - 139.
Go to original source...
- PODPROCKÁ, D., BOLIBRUCHOVÁ, D. (2018). The Role of Manganese in the Alloy Based on Al-Si-Mg with Higher Iron Content. In: Manufacturing Technology, Vol. 18, No. 4, pp. 650 - 654. ISSN 1213-2489.
Go to original source...
- RANA, R. S., PUROHIT, R., DAS, S. (2012). Reviews on the Influences of Alloying elements on the Microstructure and Mechanical Properties of Aluminum Alloys and Aluminum Alloy Composites. In: International Journal of Scientific and Research Publications, Vol. 2, No. 6, pp 1 - 7.
- EXCALERA-LOZANO, R., et al. (2010). The Role of Mg2Si in the Corrosion Behavior of Al-Si-Mg Alloys for Pressureless Infiltration. In: The Open Corrosion Journal, Vol. 3. No. 1, pp 73 - 79. ISSN: 1876-5033.
Go to original source...
- TAYLOR, J. A. (2004). The effect of iron in Al-Si casting alloys. In: 35th Australian Foundry Institute National Conference. Adelaide. 148 - 157.
- KUCHARIKOVÁ, L., et al. (2018). Role of Chemical Composition in Corrosion of Aluminum Alloys. In: Materials, Vol. 8, No. 8, pp. 1 - 13. ISSN 2075-4701.
Go to original source...
- ABBAS, M. K. (2016). Effect of Magnesium Addition on Corrosion Resistance of Aluminum -17%Silicon Alloy. In: Al-Khwarizmi Engineering Journal, Vol 12, No. 4, pp. 50 - 58.
Go to original source...
- EBHOTA, W.S., TIEN-CHIEN, J. (2018). Intermetallics Formation and Their Effect on Mechanical Properties of Al-Si-X Alloys. In: Intermetallic Compounds - Formation and Applications. London: IntechOpen. ISBN 978-1-83881-298-0.
Go to original source...
- KUSMIERCZAK, S., HREN, I. (2019). Influence of AlSi7Mg0.3 Alloy Modification on Corrosion Behaviour in the Salt Environment. In: Manufacturing Technology, Vol. 19, No. 5, pp. 802 - 806. ISSN: 1213-2489.
Go to original source...
- FOUSOVA, M., et al. (2019). Corrosion of 3D-Printed AlSi9Cu3Fe Alloy. In: Manufacturing Technology, Vol. 19, No. 1, pp. 29 - 36. ISSN 1213-2489.
Go to original source...
- PADMANABAN, D., KURIEN, G. (2012). Silumins: The Automotive Alloys. In: Advanced Materials and Processes. Vol. 170, No. 3, pp. 28 - 30. ISSN 0882-7958.
Go to original source...
- ZHU, L., et al. (2018). Lightweighting in aerospace component and system design. In: Propulsion and Power Research. Vol. 7, No. 2, pp. 103 - 119. ISSN 2212-540X.
Go to original source...
- ROBLES-HERNANDEZ, F. C., et al. (2017). Al-Si Alloys - Automotive, Aeronautical, and Aerospace Applications. Springer, Cham. ISBN 978-3-319-58379-2.
Go to original source...
- KUČERA, V., VOJTĚCH, D. (2017). Influence of heat treatment on corrosion behaviour and mechanical properties of the AA 7075 alloy. In: Manufacturing Technology. Vol. 17, No. 5, pp. 747 - 752. ISSN 1213-2489.
Go to original source...
- VANKO, B., STANČEK, L. (2012). Utilization of heat treatment aimed to spheroidization of eutectic silicon for silumin castings produced by squeeze casting. In: Archives of foundry engineering. Vol. 12, Iss. 1, pp. 111 - 114. ISSN 1897-3310.
Go to original source...
- STANČEK, L., VANKO, B., BATY©EV, A. I. (2014). Structure and properties of silumin castings solidified under pressure after heat treatment. In: Metal Science and Heat Treatment, vol. 56, No. 3-4, pp. 197 - 202.
Go to original source...
- BERLANGA-LABARI, C.; BIEZMA-MORALEDA, M. V.; RIVERO, P. J. (2020). Corrosion of Cast Aluminum Alloys: A Review. In: Metals, 10, 1384.
Go to original source...
- TAHAMTAN, S., BOOSTANI, A. F. (2009). Quantitative analysis of pitting corrosion behavior of thixoformed A356 alloy in chloride medium using electrochemical techniques. In: Materials and Design, 30, pp. 2483 - 2489.
Go to original source...
This is an open access article distributed under the terms of the Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.