Manufacturing Technology 2024, 24(4):626-635 | DOI: 10.21062/mft.2024.057

The Impact of Cryogenic Temperatures on the Hardness and Tribological Properties of Cobalt Alloys

Jakub Mráz ORCID..., Totka Bakalova ORCID...
Faculty of Mechanical Engineering, Department of Materials, Technical University of Liberec, Studentská 2, 461 17 Liberec. Czech Republic

This article explores the effect of cryogenic temperatures on the properties of cobalt alloys, specifically Stellite 6 and Stellite 12. These alloys are commonly used in applications that require resistance to me-chanical, thermal, and chemical wear. In this study, the focus is on the valve seats for internal combus-tion engines, which are made from cobalt alloys and undergo a freezing process before assembly into the cylinder head. The purpose of freezing is to reduce the diameter of valve seats, making them easier to fit into the cylinder head. However, the length of time spent in freezing can significantly affect the hardness and tribological characteristics of the material.

Keywords: Cobalt alloys, Cryogenic treatment, Tribological properties, Valve, Valve seats

Received: February 26, 2024; Revised: May 10, 2024; Accepted: June 17, 2024; Prepublished online: August 2, 2024; Published: September 1, 2024  Show citation

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Mráz J, Bakalova T. The Impact of Cryogenic Temperatures on the Hardness and Tribological Properties of Cobalt Alloys. Manufacturing Technology. 2024;24(4):626-635. doi: 10.21062/mft.2024.057.
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References

  1. BLOMBERG R., C. PERROTT (1994) Adhesive wear processes occurring during abrasion of Stellite type alloys. Journal of the Australian Institute of Metals. No. 4. p. 19.
  2. SUCHÁNEK J., et al. (2007) "Abrazivní opotřebení materialů [Abrasive Wear of Materials]. Praha: 162 pages. ISBN 970-80-01-03659-4.
  3. CHEN Z. et al. (2019) Microstructural evolution and wear behaviors of laser-clad stellite 6/NBC/h-BN self-lubricating coatings. Surface and Coatings Technology. 372. pp. 218-228. Available at: https://doi.org/10.1016/j.surfcoat.2019.04.083. Go to original source...
  4. GALE W. F., TOTEMEIER T. C. & SMALL C. (Eds.). (2011). Smithells Metals Reference Book. But-terworth-Heinemann.
  5. PORTER D. A., EASTERLING K. E. & SHERIF M. (2009). Phase Transformations in Metals and Alloys. CRC Press. Go to original source...
  6. SZALA M. & CHOCYK D. & SKIC A. & KAMIŃSKI M. & MACEK W. & TUREK M. (2021). Effect of Nitrogen Ion Implantation on the Cavitation Erosion Resistance and Cobalt-Based Solid Solution Phase Transformations of HIPed Stellite 6. Materials. 14. 2324.10.3390/ma14092324. Go to original source...
  7. MOTALLEBZADEH A. & Atar E. & Cimenoglu H. (2015). Microstructure and Tribological Properties of PTA Deposited Stellite 12 Coating on Steel Substrate. 3. 224-228. 10.13189/mst.2015.030505. Go to original source...
  8. YANG Shu, Cryogenic burnishing of Co-Cr-Mo biomedical alloy for enhanced surface integrity and improved wear performance (2012). Theses and Dissertations -Mechanical Engineering 10. Go to original source...
  9. LI X. ZHANG Y. GAO Y. & LI G. (2018). Journal of Alloys and Compounds. 766. 243-249. Go to original source...
  10. SKALANTE E.M. MAKICH H. and NOUARI M. (2022) Effect of cryogenic friction conditions on Sur-face Quality. Procedia CIRP. 108. pp. 675-680. Available at: https://doi.org/10.1016/j.procir.2022.03.105 Go to original source...
  11. MOTALLEBZADEH A. & ATAR E. & CIMENOGLU H. (2015). Microstructure and Tribological Properties of PTA Deposited Stellite 12 Coating on Steel Substrate. 3. 224-228. 10.13189/mst.2015.030505. Go to original source...
  12. SONAR T. LOMTE S. and GOGTE. C. (2018) "Cryogenic treatment of Metal - A Review." Materials Today: Proceedings. 5(11). pp. 25219-25228. Available at: https://doi.org/10.1016/j.matpr.2018.10.324. Go to original source...
  13. BAKALOVA, T., N. PETKOV, H. BAHCHEDZHIEV, P. KEJZLAR, a P. LOUDA, "Comparison of mechanical and tribological properties of TiCN and CrCN coatings deposited by CAD", Manuf. Tech-nol., roč. 16, č. 5, s. 859-864, 2016. Go to original source...
  14. BAKALOVA T., N. PETKOV, H. BAHCHEDZHIEV, P. KEJZLAR, a L. VOLESKỲ, "Monitoring Changes in the Tribological Behaviour of CrCN Thin Layers with Different CH4/N2 Gas Ratios at Room and Elevated Temperatures", Manuf. Technol., roč. 18, č. 4, s. 533-537, 2018. Go to original source...
  15. KRAFKA, M. et al. "Comparison of Mechanical and Tribological Properties of TiN and ZrN Coatings Deposited by Arc-PVD", Manuf. Technol., roč. 23, č. 2. s. 194 - 203, 2023. Go to original source...
  16. EN ISO 6508-1 European Committee for Standardization (CEN). (2016). Metallic materials - Rockwell hardness test - Part 1: Test method (ISO 6508-1:2016). EN ISO 6508-1. Brussels: European Committee for Standardization.
  17. ASTM E 140-97. ASTM International. (1997). Standard Hardness Conversion Tables for Metals Relation-ship Among Brinell Hardness, Vickers Hardness, Rockwell Hardness, Superficial Hardness, Knoop Hardness, and Scleroscope Hardness. ASTM E 140-97. West Conshohocken, PA: ASTM International.
  18. ASTM G99-95, 2000. Standard Test Method for Wear Testing with a Pin-on-Disc Apparatus. ASTM International, 6 pages.
  19. BAKALOVA T., P. LOUDA, L. VOLESKỲ, K. BORŮVKOVÁ, a L. SVOBODOVÁ, "Nanoadditives SiO2 and TiO2 in Process Fluids", Manuf. Technol., roč. 15, č. 4, s. 502-508, 2015. Go to original source...
  20. SASSATELLI P., G. BOLELLI, M. LASSINANTTI GUALTIERI, E. HEINONEN, M. HONKANEN, L. LUSVARGHI, T. MANFREDINI, R. RIGON, M. VIPPOLA, Properties of HVOF-sprayed Stellite-6 coatings, Surf. Coat. Technol. 338 (2018) 45-62, https://doi.org/10.1016/j.surfcoat.2018.01.078. Go to original source...
  21. BOLELLI G., V. CANNILLO, L. LUSVARGHI, M. MONTORSI, F.P. MANTINI, M. BARLETTA, Microstructural and tribological comparison of HVOF-sprayed and post-treated M-Mo-Cr-Si (M=Co, Ni) alloy coatings, Wear 263 (2007) 1397-1416, https://doi.org/10.1016/j.wear.2006.12.002. Go to original source...
  22. SINGH H., B.S. SIDHU, S. PRAKASH, Performance of HVOF sprayed NiCr and Stellite-6 coatings under pin on disc wear testing, Mater. Sci. Forum 701 (2012) 21-29, https://doi.org/10.4028/www.scientific.net/MSF.701.21. Go to original source...
  23. EN 1071-13:2010, 2010. Advanced Technical Ceramics. Methods of Test for Ceramic Coatings. Determination of Wear Rate by the Pin-on-Disc Method.

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