Manufacturing Technology 2024, 24(6):914-928 | DOI: 10.21062/mft.2024.097
Effect of Heat Treatment and Corrosion Load on the Microstructure of the Ti6Al4V Alloy
- Faculty of Mechanical Engineering, J. E. Purkyne University in Usti nad Labem. Pasteurova 3334/7, 400 01 Usti nad Labem. Czech Republic
Titanium and its alloys are an important structural material in all sectors of industry. Thanks to its mechanical properties. One of the most widely used titanium alloys is the Ti6Al4V alloy. If we heat alloys for a long time in an air atmosphere, TiO2 is formed on the surface of the parts. The Ti6Al4V alloy, also referred to as Ti64, is a two-phase alloy formed by α+β solid solutions from the point of view of microstructure, it is characterized by corrosion resistance and good biocompatibility. Through heat treatment, we can improve the mechanical properties of the alloy, improve the fracture toughness, influence and reduce the internal stress and influence the machinability of the material. To achieve a longer service life of products made of this alloy, we can use the method of surface treatment, in the form of nano layers. An analysis of the Ti6Al4V alloy was performed for the cell, after heat treatment at temperatures of 650 °C and 800 °C and followed by corrosion loading in a salt fog environment. The exposure time in the corrosive environment was between 168 and 720 hours. Changes in the microstructure were ob-served and the change in microhardness in the surface layers of Ti6Al4V was described.
Keywords: Ti6Al4V, Microstructure, SEM and EDS analysis, Microhardness, Corrosion load
Grants and funding:
This article was supported by SGS UJEP-SGS-2021-48-002-3
Received: September 12, 2023; Revised: November 28, 2024; Accepted: December 2, 2024; Prepublished online: December 5, 2024; Published: December 21, 2024 Show citation
References
- PRYMAK, O., BOGDANSKI, D., KÖLLER, M., ESENWEIN, S., & col. (2005). Morphological characterization and in vitro biocompatibility of a porous nickel-titanium alloy. Biomaterials, Vol. 26, Issue 29, pp. 5801-5807. ISSN 0142-9612.
Go to original source...
- BROOKSHIRE, F. V. G., NAGY, W. W., DHURU, V. B., ZIEBERT, G. J., CHADA, S. (1997). The qualitative effects of various types of hygiene instrumentation on commercially pure titanium and titanium alloy implant abutments: an in vitro and scanning electron microscope study.
- LEYENS, C., PETERS, M. (2003). Titanium and titanium alloys, Fundamental and applications. WILEY-VCH, pp. 333-350, 401-404. ISBN: 9783527602117.
Go to original source...
- KUSMIERCZAK S., SRB R. Influence of Thermomechanical Processing Parameters on Selected Properties of B-post Made of 22MnB5 Steel. Manufacturing Technology. 2023;23(6):837-845. doi: 10.21062/mft.2023.105.
Go to original source...
- XIAOGUANG, F., QI, L., ANMING, Z., YUGUO, S., WENJIA M. (2017). The Effect of Initial Structure on Phase Transformation in Continuous Heating of a TA15 Titanium Alloy. Metals, Vol. 7, No. 6, pp. 1-12. ISSN 2075-4701.
Go to original source...
- PEDERSON, R., BABUSHKIN O., SKYSTEDT F. AND WARREN R. (2003). Use of High Temperature X-ray Diffractometry to Study Phase Transitions and Thermal Expansion Properties in Ti - 6Al - 4V. Materials Science and Technology, Vol.19, No. 11, pp. 1533-1538.
Go to original source...
- LEE, K., YANG, S., YANG, J. (2017) Optimization of Heat-treatment Parameters in Hardening of Titanium Alloy Ti-6Al-4V by using the Taguchi Method. International Journal of Advanced Manufacturing and Technology, Vol. 90, pp. 753-761.
Go to original source...
- HUA, Q., WEIDONG, L. (2011) Theoretical Calculation of β Transition Temperature of Ti-6Al-4V from Valence Electron Level. Advanced Materials Research, pp. 299-300, ISSN: 1662-8985.
Go to original source...
- FIDAN, S., AVCU, E., KARAKULAK, E., YAMANOGLU, R., ZEREN M., SINMAZCELIK T. (2013). Effect of Heat Treatment on Erosive Wear Behaviour of Ti6Al4V alloy. Materials Science and Technology, Vol. 29, No. 9, pp. 1088-1094.
Go to original source...
- Imam, M. A., Gilmore, C. M., (1983) Fatigue and Microstructural Properties of Quenched Ti-6AI-4V. Metallurgical Transactions A, Vol. 14, pp. 223-240.
Go to original source...
- SUDHAGARA, R. S., JITHIN, V., GEETHA, M., NAGESWARA R. M. (2018). Processing of Beta Titanium Alloys for Aerospace and Biomedical Applications. Titanium Alloys - Novel Aspects of Their Manufacturing and Processing Intech, Open 1-18.
- HADKE, S., KHATIRKAR, R. K., SHEKHAWAT, S. K., JAIN, S., SAPATE, S. G. (2015) Microstructure Evolution and Abrasive Wear Behavior of Ti-6Al-4V Alloy. Journal of Materials Engineering and Performance, Vol. 24, pp. 3969-3981.
Go to original source...
- SEMIATIN, S. L., KNISLEY, S. L., FAGIN, P. N., ZHANG, F., BARKER D. R. (2003). Microstructure Evolution during Alpha-Beta Heat Treatment of Ti-6Al-4V. Metallurgical and Materials Transactions A, Vol. 34, pp. 2377-2386.
Go to original source...
- QU, S. G., SUN, F. J., YUAN, Z. M., LI, G., LI Q. (2015). Effect of Annealing Treatment on Microstructure and Mechanical Properties of Hot Isostatic Pressing Compacts Fabricated using Ti-6Al-4V Powder. Powder Metallurgy, Vol. 58, No. 4, pp. 312-319.
Go to original source...
- JOVANOVIC, M. T., TADIĆ, S., ZEC S., MI©KOVIC, Z., BOBIĆ I. (2006). The Effect of An-nealing Temperatures and Cooling Rates on Microstructure and Mechanical Properties of Investment Cast Ti-6Al-4V Alloy. Materials and Design, Vol. 27, No. 3, pp. 192-199. ISSN 0261-3069.
Go to original source...
- RAJAGOPAL, K. P. A., JOSE, A. M., SOMAN, A., DCRUZ, C. J., NIVED, S. N., SYAMRAJ, S., VIMALKUMAR P. (2015). Investigation of Physical and Mechanical Properties of Ti Alloy (Ti-6Al-4V) Under Precisely Controlled Heat Treatment Processes. International Journal of Mechanical Engineering and Technology, Vol. 6, No. 2, pp. 116-127. ISSN 0976 - 6359.
- KLIMAS, J., SZOTA, M., NABIAŁEK, M., ŁUKASZEWICZ, A., BUKOWSKA, A. (2013). Comparative description of structure and properties of Ti6Al4V titanium alloy for biome dical ap-plications produced by two methods: conventional (molding) and innovative (injection) ones, Jour-nal of Achievements in Materials and Manufacturing Engineering. Vol. 61, No. 2, pp. 195-201.
Go to original source...
- GARCIA-ALONSO, M., C., In vitro corrosion behaviour and osteoblast response of thermally oxidized Ti6Al4V alloy, Madrid, Biomaterials, 2003.
Go to original source...
- BLOYCE, A., Surface modification of titanium alloys for combined improvements in corrosion and wear resistance, Birmingham, Surface and Coatings Technology, 1999.
- MASHEKOVA A., NURTAZAEV A., MASHEKOV S., ALSHYNOVA A., TUSSUPKALIYEVA E. The Influence of the Technological Parameters of Rolling in the Helical Rollers and Longitudinal Wedge Mill on the Quality of Two-Phase Titanium Alloy. Manufacturing Technology. 2017;17(3):347-354. doi: 10.21062/ujep/x.2017/a/1213-2489/MT/17/3/347.
Go to original source...
- Hren I., Ku¶mierczak S., Horký R. Use of Electron Microscopy in the Analysis of the Influence of Roughness on the Corrosion Behavior of Selected Ti Alloys. Manufacturing Technology. 2023;23(2):161-176. doi: 10.21062/mft.2023.017.
Go to original source...
- CHEN, J., PAN, C. (2011). Welding of Ti-6Al-4V alloy using dynamically controlled plasma arc welding process. Transactions of Nonferrous Metals Society of China, Vol. 21, No. 7, pp. 1506-1512. ISSN 1003-6326.
Go to original source...
- WU, M., XIN, R., WANG, Y., ZHOU, Y., WANG, K., LIU Q. (2016). Microstructure, texture and mechanical properties of commercial high-purity thick titanium plates jointed by electron beam welding. Materials Science and Engineering, Vol. 677, pp. 50-57.
Go to original source...
- SQUILLACE, A., PRISCO, U., CILIBERTO, S., ASTARITA, A. (2012). Effect of welding parameters on morphology and mechanical properties of Ti-6Al-4V laser beam welded butt joints. Journal of Materials Processing Technology, Vol. 212, pp. 427-436. ISSN 0924-0136.
Go to original source...
- KASHAEV, N., VENTZKE, V., FOMICHEV, V., FOMIN, F., RIEKEHR. S. (2016). Effect of Nd:YAG laser beam welding on weld morphology and mechanical properties of Ti-6Al-4V butt joints and T-joints. Optics and Lasers in Engineering, Vol. 86, pp.172-180.
Go to original source...
- LI, X., XIE, J., ZHOU, Y. (2005). Effect of oxygen contamination in the argon shielding gas in laser welding of commercially pure titanium thin sheet. J Mater Sci, Vol. 40, pp. 3437-3443.
Go to original source...
- DAI, N., ZHANG, L. C., ZHANG, J., CHEN, Q., WU, M. (2016). Corrosion behavior of selective laser melted Ti-6Al-4 V alloy in NaCl solution. Corros. Sci., Vol. 102, pp. 484-489.
Go to original source...
- BAI, Y., GAI, X., LI, S., ZHANG, L. C., LIU, Y., HAO, Y., ZHANG, X., YANG, R., GAO, Y. Improved corrosion behaviour of electron beam melted Ti-6Al-4V alloy in phosphate buffered saline. Corrosion Science, Vol. 123, pp 289-296. ISSN 0010-938X.
Go to original source...
- ZIELIŃSKI, A., SOBIESZCZYK, S. (2010). Corrosion of Titanium Biomaterials, Mechanisms, Effects and Modelisation. Corrosion Reviews, Vol. 26, pp 1-22.
Go to original source...
- KOUŘIL, M. (2011). Corrosion rate of construction materials in hot phosphoric acid with the contribution of anodic polarization. Weinheim. Materials and Corrosion, Vol. 63, No. 4, pp. 310-316.
Go to original source...
- KRYSHNA, D. S. R. (2006). Thick rutile layer on titanium for tribological applications. Tribology International, Vol. 40, No. 2, pp 329-334. Singapore. ISSN 0301-679X.
Go to original source...
- ČSN ISO 8407: Koroze kovů a slitin, Odstraňování korozních zplodin ze vzorků podrobených korozním zkouąkám. Leden 1995. Praha: Český normalizační institut, 1995,12 s.
- ČSN 03 8212: Zabezpečování jakosti korozních zkouąek v umělých atmosférách. Praha: Český normalizační institut, 1994.
- KRYSHNA, D., S., R., Thick rutile layer on titanium for tribological applications, Singapore, Tribology International, 2006.
- VELTEN, D., Preparation of TiO2 layers on CP-Ti and Ti6Al4V by thermal and anodic axidation and by sol-gel coating techniquest and their characterization, Saarbücken, Wiley Online Library, 2001.
Go to original source...
This is an open access article distributed under the terms of the Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.