Manufacturing Technology 2018, 18(5):758-763 | DOI: 10.21062/ujep/173.2018/a/1213-2489/MT/18/5/758

Phase Composition and Microstructure of Zn Coated Press Hardening Steels for Direct Hot Stamping

Vojtěch Kučera1, Jaroslav Pert-Soini2, Dalibor Vojtěch1
1 University of Chemistry and Technology, Prague, Department of Metals and Corrosion Engineering, Czech Republic, EU
2 ŠKODA AUTO a. s., Mladá Boleslav, Czech Republic, EU

Decarburization and oxidation occur during production of press hardening steels (PHS) used in automotive. Therefore, coatings are applied on the steel surface to prevent this. The most common Zn coatings have not been processable by available direct hot stamping technology ordinarily used to produce the PHS and have been replaced by Al-Si coatings. However, the Al-Si coatings have a negative impact on joining technologies and further processing. Recently, the modification of direct hot stamping, which enables process the PHS with Zn coatings, was introduced. We investigated the microstructure, phase composition and distribution of particular phases (SEM-EDS, XRD), as well as micro-hardness of the Zn coated PHS prepared by the modified direct hot stamping. The PHS revealed the coating with 25 ± 3 μm thickness and continuous interface consisting of α-Fe(Zn) solid solution, Γ and Γ1 intermetallic phases and zinc oxides enriched with manganese. The thorough description of the material is important in development of further processing steps such as joining technologies and corrosion resistance.

Keywords: Zn coating, press hardening steels, direct hot stamping, liquid metal embrittlement

Published: October 1, 2018  Show citation

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Kučera V, Pert-Soini J, Vojtěch D. Phase Composition and Microstructure of Zn Coated Press Hardening Steels for Direct Hot Stamping. Manufacturing Technology. 2018;18(5):758-763. doi: 10.21062/ujep/173.2018/a/1213-2489/MT/18/5/758.
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References

  1. H. KARBASIAN, A.E. TEKKAYA. (2010). A review on hot stamping. In: Journal of Materials Processing Technology, Vol. 210, No. 15, pp. 2103-2118 Go to original source...
  2. V.H. LÓPEZ-CORTÉZ, F.A. REYES-VALDÉS. (2008). Understanding Resistance Spot Welding of Advanced High-Strength Steels, 36-40.
  3. P. HANUS, E. SCHMIDOVÁ. (2016). Influence of the welding process on the martensitic and dual phase high strength steels. In: Manufacturing Technology, Vol. 16, No. 4, pp. 702-707 Go to original source...
  4. J. MENDALA. (2012). Liquid metal embrittlement of steel with galvanized coatings. In: IOP Conf. Series: Materials Science and Engineering, Vol. 35, No., pp. 1 - 8 Go to original source...
  5. L. CHO, et al. (2014). Microstructure of liquid metal embrittlement cracks on Zn-coated 22MnB5 press-hardened steel. In: Scripta Materialia, Vol. 90-91, No., pp. 25-28 Go to original source...
  6. Z.-X. GUI, W.-K. LIANG, Y.-S. ZHANG. (2014). Formability of aluminum-silicon coated boron steel in hot stamping process. In: Transactions of Nonferrous Metals Society of China, Vol. 24, No. 6, pp. 1750-1757 Go to original source...
  7. C. KIM, M.J. KANG, Y.D. PARK. (2011). Laser welding of Al-Si coated hot stamping steel. In: Procedia Engineering, Vol. 10, No., pp. 2226-2231 Go to original source...
  8. Z. GUI, W. LIANG, Y. ZHANG. (2014). Enhancing ductility of the Al-Si coating on hot stamping steel by controlling the Fe-Al phase transformation during austenitization. In: Science China Technological Sciences, Vol. 57, No. 9, pp. 1785-1793 Go to original source...
  9. H. PING, Y. LIANG, H. BIN. (2017). Hot Stamping Advanced Manufacturing Technology of Lightweight Car Body, XVI, 314. Springer Singapore.
  10. W. STEED. Hot off the press. 2014 [cited 2018 18.06.] ; Available from: https://automotivemanufacturingsolutions.com/technology/hot-off-the-press.
  11. E.F. WILLIAM. New coil-applied nonmetallic coating protects press-hardenable steel. 2015 [cited 2018 29.05.]; Available from: https://www.thefabricator.com/article/metalsmaterials/new-coil-applied-nonmetallic-coating-protects-press-hardenable-steel.
  12. T. KURZ, et al. (2016). Press-hardening of zinc coated steel - characterization of a new material for a new process. In: IOP Conference Series: Materials Science and Engineering, Vol. 159, No. 1, pp. 012025 Go to original source...
  13. G. HENSEN, et al., Unlocking the potential of zinc coated steel for hot forming by innovative process modifications, in CHS2 2015, 5th International Conference on Hot Sheet Metal Forming of High-Performance Steel. 2015, erlag Wissenschaftliche Scripten: Toronto. p. 85-92.
  14. Y.K. BUDIONO, S.Y. MARTOWIBOWO. (2017). Optimization of Resistance Spot Welding process using Response Surface Methodology and Simulated Annealing. In: Manufacturing Technology, Vol. 17, No. 4, pp. 434-440 Go to original source...
  15. H. JIRKOVÁ, et al. (2018). Use of the press hardening technology for treatment of TRIP steel. In: Manufacturing Technology, Vol. 18, No. 2, pp. 243-247 Go to original source...
  16. C.E. JORDAN, et al. (1993). Metallographic preparation technique for hot-dip galvanized and galvannealed coatings on steel. In: Materials Characterization, Vol. 31, No. 2, pp. 107-114 Go to original source...
  17. P. POKORNY, et al. (2015). Description of structure of Fe-Zn intermetalic compounds present in hot-dip galvanized coatings on steel. In: Metalurgija, Vol. 54, No. 4, pp. 707-710
  18. A.R. MARDER. (2000). The metallurgy of zinc-coated steel. In: Progress in Materials Science, Vol. 45, No. 3, pp. 191-271 Go to original source...
  19. J.D. CULCASI, et al. (1999). Control of the growth of zinc-iron phases in the hot-dip galvanizing process. In: Surface and Coatings Technology, Vol. 122, No. 1, pp. 21-23 Go to original source...

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