Manufacturing Technology 2017, 17(5):838-842 | DOI: 10.21062/ujep/x.2017/a/1213-2489/MT/17/5/838
Formation of Phases in Ti-Al System at 800 °C
- University of Chemistry and Technology in Prague, Department of Metals and Corrosion Engineering, Technická 5, 166 28 Prague 6, Czech Republic
In this work, kinetics of the intermediary phase formation in Ti-Al system during reactive sintering at 800 °C was investigated. Because it is very difficult to determine the kinetics on the powder mixture, special model system was utilized. This model consisted of solid titanium and molten aluminium and the intermediary phase formation was observed on the interface solid - liquid state at various times. Only TiAl3 phase formed during the test. The thickness of the layer was changing and based on these results it can be estimated how the process is controlled. It was revealed that the formation of TiAl3 phase is controlled by the rate of chemical reaction and the incubation period is 5 and 75 min.
Keywords: Kinetics, Intermediary Phases, Aluminides, Reactive Sintering
Published: October 1, 2017 Show citation
References
- LAGOS, M. A., AGOTE, I., SAN JUAN, J. M., HENNICKE, J. (2014). Fabrication of TiAl alloys by alternative powder methods. In: Gamma Titanium Aluminide Alloys 2014: A Collection of Research on Innovation and Commercialization of Gamma Alloy Technology, pp. 77 - 82. Wiley Online Library. USA.
Go to original source...
- KVANIN, V. L., BALIKHINA, N. T., VADCHENKO, S. G., BOROVINSKAYA, I. P., SYCHEV, A. E. (2008). Preparation of γ-TiAl intermetallic compounds through Self-Propagating High-Temperature Synthesis and compaction. In: Inorganic Materials, Vol. 44, No. 11, pp. 1327 - 1331. Springer. Germany.
Go to original source...
- HASHIMOTO, K., KIMURA, M., SUYAMA, R. (1994). Alloy design of gamma titanium aluminide intermetallic compounds. In: Nippon Steel Technical Report, No. 62, pp. 98 - 103. Nippon Steel & Sumitomo Metal. Japan.
- SIEMIASZKO, D., MOŚCICKI, R. (2015). Kinetics study on the SHS reaction in massive samples with high heating rate in the Fe-Al system. In: Journal of Alloys and Compounds, Vol. 632, pp. 335 - 342. Elsevier. Netherlands.
Go to original source...
- ŠKOLÁKOVÁ, A., NOVÁK, P., SALVETR, P. (2016). Influence of elements with high affinity to oxygen on microstructure and phase composition of Ni-Ti alloy. In: Manufacturing technology, Vol. 16, No. 4, pp. 808 - 814. UJP. Czech Republic.
Go to original source...
- ŠKOLÁKOVÁ, A., NOVÁK, P., SALVETR, P. (2016). Thermal analysis of Ni-Ti-X alloys prepared by Self-propagating High-temperature Synthesis. In: Manufacturing technology, Vol. 16, No. 5, pp. 1146 - 1150. UJP. Czech Republic.
Go to original source...
- ŠKOLÁKOVÁ, A., SALVETR, P., NOVÁK, P. (2017). Alloying by magnesium: A route how to eliminate the amount of Ti2Ni phase in Ni-Ti alloy. In: Manufacturing technology, In press. UJP. Czech Republic.
Go to original source...
- SALVETR, P., DANEY, B., NOVÁK, P. (2016). Comparison of Ni-Ti-Si alloy prepared by various powder metallurgy routes. In: Manufacturing technology, Vol. 16, No. 5, pp. 1136 - 1140. UJP. Czech Republic.
Go to original source...
- SALVETR, P., ŠKOLÁKOVÁ, A., NOVÁK, P. (2016). Changes in microstructure and properties of Ni-Ti alloy after addition of ternary alloying element. In: Manufacturing technology, Vol. 16, No. 6, pp. 1359 - 1363. UJP. Czech Republic.
Go to original source...
- NOVÁK, P., POPELA, T., KUBÁSEK, J., ŠERÁK, J., VOJTĚCH, D., MICHALCOVÁ, A. (2011). Effect of reactive sintering conditions on microstructure of in situ titanium aluminide and silicide composites. In: Powder Metallurgy, Vol. 54, No. 1, pp. 50 - 55. Taylor & Francis Online. United Kingdom.
Go to original source...
- GENNARI, S., MAGLIA, F., ANSELMI-TAMBURINI, U., SPINOLO, G. (2003). Self-Propagating High-Temperature Synthesis of intermetallic compounds: A computer simulation approach to the chemical mechanisms. In: The Journal of Physical Chemistry B, Vol. 107, No. 3, pp. 732 - 738. ACS Publications. USA.
Go to original source...
- ALMAN, D. E. (2005). Reactive sintering of TiAl-Ti5Si3 in situ composites. In: Intermetallics, Vol. 13, No. 6, pp. 572 - 579. Elsevier. Netherlands.
Go to original source...
- YANG, W. Y., WEATHERLY, G. C. (1996). A study of combustion synthesis of Ti-Al intermetallic compounds. In: Journal of Material Science, Vol. 31, No. 14, pp. 3707 - 3713. Springer. Germany.
Go to original source...
- YI, H. C., PETRIC, A., MOORE, J. J. (1992). Effect of heating rate on the combustion synthesis of Ti-Al intermetallic compounds. In: Journal of Materials Science, Vol. 27, No. 24, pp. 6797 - 6806. Springer. Germany.
Go to original source...
- WANG, T., LU, Y. X., ZHU, M. L., ZHANG, J. S., JI, S. J. (2002). DSC research on critical temperature in thermal explosion synthesis reaction Ti+3Al→TiAl3. In: Journal of Thermal Analysis and Calorimetry, Vol. 67, No. 3, pp. 605 - 611. Springer. Germany.
Go to original source...
- PENG, L. M., WANG, J. H., LI, H., ZHAO, J. H., HE, L. H. (2005). Synthesis and microstructural characterization of Ti-Al3Ti metal intermetallic laminate (MIL) composites. In: Scripta Materialia, Vol. 52, No. 3, pp. 243 - 248. Elsevier. Netherlands.
Go to original source...
- SOHN, H. Y., WANG, X. (1996). Mathematical and experimental investigation of the self-propagating high-temperature synthesis (SHS) of TiAl3 and Ni3Al intermetallic compounds. In: Journal of Materials Science, Vol. 31, No. 12, pp. 3281 - 3288. Springer. Germany.
Go to original source...
- MA, Y., FAN, Q., ZHANG, J., SHI, J., XIAO, G., GU, M. (2008). Microstructural evolution during self-propagating high-temperature synthesis of Ti-Al system. In: Journal of Wuhan University of technology - Materials Science Edition, Vol. 23, No. 3, pp. 381 - 385. Springer. Germany.
Go to original source...