Manufacturing Technology 2018, 18(3):499-503 | DOI: 10.21062/ujep/128.2018/a/1213-2489/MT/18/3/499

The Effect of Aluminium Amount on the Combustion Temperature and Microstructure of Ti-Al alloy After Reactive Sintering

Andrea Školáková, Pavel Salvetr, Pavel Novák
University of Chemistry and Technology in Prague, Department of Metals and Corrosion Engineering, Technická 5, 166 28 Prague 6, Czech Republic

Titanium aluminides with various amounts of aluminium were prepared by Self-propagating High-temperature Synthesis (SHS). Ti-20 wt. % Al, Ti-38 wt. % Al and Ti-63 wt. % Al were chosen according to Ti-Al phase diagram, because these chemical compositions represent Ti3Al, TiAl and TiAl3 phase, respectively. The effect of the amount of aluminium on the combustion temperatures, microstructure and phase composition was studied. Heating of compressed samples was observed by optical pyrometer to determine exothermic reaction which is associated with SHS reaction. It was found that reaction temperatures increased with increasing addition of aluminium as well as reaction time and the start of ignition. The expected dominant phases were determined in all systems after SHS reaction. However, other phases accompanied their formation. The largest variety of phases formed in Ti-38 wt. % Al system.

Keywords: Ti-Al alloy, combustion temperature, Self-propagating High-temperature Synthesis

Published: June 1, 2018  Show citation

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Školáková A, Salvetr P, Novák P. The Effect of Aluminium Amount on the Combustion Temperature and Microstructure of Ti-Al alloy After Reactive Sintering. Manufacturing Technology. 2018;18(3):499-503. doi: 10.21062/ujep/128.2018/a/1213-2489/MT/18/3/499.
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References

  1. HASHIMOTO, K., KIMURA, M., SUYAMA, R. (1994). Alloy design of gamma titanium aluminide intermetallic compounds. In: Nippon Steel Technical Report, No. 62, pp. 98 - 103. Nippon Steel & Sumitomo Metal. Japan.
  2. LAGOS, M. A., AGOTE, I., SAN JUAN, J. M., HENNICKE, J. (2014). Fabrication of TiAl alloys by alternative powder methods. In: Gamma Titanium Aluminide Alloys 2014: A Collection of Research on Innovation and Commercialization of Gamma Alloy Technology, pp. 77 - 82. Wiley Online Library. USA.
  3. BEWLAY, B. P., NAG, S., SUZUKI, A., WEIMER, M. J. (2016). TiAl alloys in commercial aircraft engines. In: Materials at High Temperatures, Vol. 33, No. 4-5, pp. 549 - 559. Taylor & Francis Online. United Kingdom. Go to original source...
  4. KVANIN, V. L., BALIKHINA, N. T., VADCHENKO, S. G., BOROVINSKAYA, I. P., SYCHEV, A. E. (2008). Preparation of γ-TiAl intermetallic compounds through Self-Propagating High-Temperature Synthesis and compaction. In: Inorganic Materials, Vol. 44, No. 11, pp. 1327 - 1331. Springer. Germany. Go to original source...
  5. ŠKOLÁKOVÁ, A., NOVÁK, P., SALVETR, P. (2016). Influence of elements with high affinity to oxygen on microstructure and phase composition of Ni-Ti alloy. In: Manufacturing technology, Vol. 16, No. 4, pp. 808 - 814. UJP. Czech Republic. Go to original source...
  6. ŠKOLÁKOVÁ, A., NOVÁK, P., SALVETR, P. (2016). Thermal analysis of Ni-Ti-X alloys prepared by Self-propagating High-temperature Synthesis. In: Manufacturing technology, Vol. 16, No. 5, pp. 1146 - 1150. UJP. Czech Republic. Go to original source...
  7. SALVETR, P., ŠKOLÁKOVÁ, A., NOVÁK, P. (2016). Changes in microstructure and properties of Ni-Ti alloy after addition of ternary alloying element. In: Manufacturing technology, Vol. 16, No. 6, pp. 1359 - 1363. UJP. Czech Republic. Go to original source...
  8. SALVETR, P., DANEY, B., NOVÁK, P. (2016). Comparison of Ni-Ti-Si alloy prepared by various powder metallurgy routes. In: Manufacturing technology, Vol. 16, No. 5, pp. 1136 - 1140. UJP. Czech Republic. Go to original source...
  9. YANG, W. Y., WEATHERLY, G. C. (1996). A study of combustion synthesis of Ti-Al intermetallic compounds. In: Journal of Material Science, Vol. 31, No. 14, pp. 3707 - 3713. Springer. Germany. Go to original source...
  10. WANG, T., LIU, R. Y., ZHU, M. L., ZHANG, J. S. (2002). Activation energy of self-heating process studied by DSC. Combustion synthesis mixture of Ti-75 at% Al. In: Journal of Thermal Analysis and Calorimetry, Vol. 70, No. 2, pp. 507 - 519. Springer. Germany. Go to original source...
  11. PENG, L. M., WANG, J. H., LI, H., ZHAO, J. H., HE, L. H. (2005). Synthesis and microstructural characterization of Ti-Al3Ti metal intermetallic laminate (MIL) composites. In: Scripta Materialia, Vol. 52, No. 3, pp. 243 - 248. Elsevier. Netherlands. Go to original source...
  12. MA, Y., FAN, Q., ZHANG, J., SHI, J., XIAO, G., GU, M. (2008). Microstructural evolution during self-propagating high-temperature synthesis of Ti-Al system. In: Journal of Wuhan University of technology - Materials Science Edition, Vol. 23, No. 3, pp. 381 - 385. Springer. Germany. Go to original source...
  13. SUJATA, M., BHARGAVA, S., SANGAL, S. (1997). On the formation of TiAl3 during reaction between solid Ti and liquid Al. In: Journal of Materials Science Letters, Vol. 16, No. 14, pp. 1175 - 1178. Springer. Germany. Go to original source...
  14. SOHN, H. Y., WANG, X. (1996). Mathematical and experimental investigation of the self-propagating high-temperature synthesis (SHS) of TiAl3 and Ni3Al intermetallic compounds. In: Journal of Materials Science, Vol. 31, No. 12, pp. 3281 - 3288. Springer. Germany. Go to original source...
  15. ŠKOLÁKOVÁ, A., SALVETR, P., NOVÁK, P., NÝVLTOVÁ, M. (2017). Formation of phases in Ti-Al system at 800 °C. In: Manufacturing Technology, Vol. 17, No. 5, pp. 838 - 842. UJP. Czech Republic.
  16. YI, H. C., PETRIC, A. (1992). Effect of heating rate on the combustion synthesis of Ti-Al intermetallic compounds. In: Journal of Materials Science, Vol. 27. No. 24, pp. 6797 - 6806. Springer. Germany. Go to original source...
  17. WANG, T., LU, Y. X., ZHU, M. L., ZHANG, J. S., JI, S. J. (2002). DSC research on critical temperature in thermal explosion synthesis reaction Ti+3Al→TiAl3. In: Journal of Thermal Analysis and Calorimetry, Vol. 67, No. 3, pp. 605 - 611. Springer. Germany. Go to original source...
  18. VARMA, A., LEBRAT, J.-P. (1992). Combustion synthesis of advanced materials. In: Chemical Engineering Science, Vol. 47, No. 9 - 11, pp. 2179 - 2194. Elsevier. Netherlands. Go to original source...
  19. KATTNER, U. R., LIN, J.-C., CHANG, Y. A. (1992). Thermodynamic assessment and calculation of the Ti-Al system. In: Metallurgical Transactions, Vol. 23, No. 8, pp. 2081 - 2090. Springer. Germany. Go to original source...
  20. MASSALSKI, T. B. (1990). Binary Alloy Phase Diagrams, ASM, Materials Park.

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